; Gibson, E.S., Identification of polycyclic aromatic compounds in of poly-mutagenic emissions from steel casting, Biomed. ; Sheldrake, C.P. Reference Material Type. ; Zhao, C.-X. Format. Before Abbreviated "phen", it is used as a ligand in coordination chemistry, forming strong complexes with most metal ions. Sun K, et al. Dupuy J, et al. Food Chem., 46, 1998, 1276-1285. class: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Description: 90C (1min) => 10C/min => 120C => 4C/min => 310C (20min); CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Zamperlini, G.C.M. and Castellano, F.N. 7uTCpb60dF$+j]nDY0U!u',6 vp`7) Naphthalene, Phenanthrene, and Anthracene" J. Phys. Res. Based on 160 references, this review covers the phytochemistry and pharmacology of 213 naturally occurring phenanthrenes that have been . Biological monitoring of exposure to polycyclic aromatic hydrocarbons by determination of unmetabolized compounds in urine. x6t:6By,M@!"x}~}pW2x8nF' 2022;22(11):939-956. doi: 10.2174/1568026621666210813113918. ; Hutfliess, M.; Hedden, K., Retention index system, adsorption characteristics, and sructure correlations of polycyclic aromatic hydrocarbons in fuels, J. Hi. endobj
; Phenanthrene CAS Number: 85-01-8 What is phenanthrene? analysis of middle oil fractions, Fuel, 76(5), 1997, 415-423. umn class: Standard non-polar; Column diameter: 0.33 mm; Column length: 25 m; Column type: Capillary; Start T: 180 C; CAS no: 85018; Active phase: SE-30; Carrier gas: N2; Data type: Kovats RI; Authors: Korhonen, I.O.O. 1,10-Phenanthroline (phen) is a heterocyclic organic compound. J Agric Food Chem. [8] The pink complex [Ni(phen)3]2+ has been resolved into its and isomers. A photoelectric conversion element according to the present invention is obtained by laminating an . ; Sun, K.-J. Temperature (K) A B C Reference Comment; 373. ; Liang, Y.-Z. This website collects cookies to deliver a better user experience. and 9 in (a) C6 glioblastoma and (b) SH-SY5Y neuroblastoma cells. Roum. endstream
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A classic and well established explanation is based on Clar's rule. 2023 Feb 9;15(4):883. doi: 10.3390/nu15040883. Chemsrc provides Phenanthrene(CAS#:85-01-8) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. MSDS/SDS Database Search |
Chromatogr., 66, 1972, 43-53. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 50 C; End T: 280 C; CAS no: 85018; Active phase: HP-5 MS; Carrier gas: Helium; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Zhao, C.; Zeng, Y.; Wan, M.; Li, R.; Liang, Y.; Li, C.; Zeng, Z.; Chau, F.-T., Comparative analysis of essential oils from eight herbal medicines with pungent flavor and cool nature by GC-MS and chemometric resolution methods, J. Sep. Pyrene forms during incomplete combustion of organic compounds. If you would like a response, please include your email address e.g. Chim., 45(4), 2000, 313-318. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 15 m; Column type: Capillary; Heat rate: 50 K/min; Start T: 50 C; End T: 320 C; End time: 1 min; Start time: 0.5 min; CAS no: 85018; Active phase: CP Sil 8 CB; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Vreuls, R.J.J. By contrast, neocuproine and bathocuproine form 1:1 complexes such as [Ni(neocuproine)Cl2]2. Environ Pollut. A, 1096, 2005, 76-85. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 80 C; End T: 290 C; CAS no: 85018; Active phase: HP-5MS; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Zhao, C.-X. Educ., 76(12), 1999, 1695-1696. class: Semi-standard non-polar; Column diameter: 0.31 mm; Column length: 25 m; Column type: Capillary; Description: 50C(2min)=>(20C/min)=>120C=>(7C/min)=>310C(10min); CAS no: 85018; Active phase: 5 % Phenyl methyl siloxane; Carrier gas: He; Phase thickness: 0.52 um; Data type: Linear RI; Authors: Yasuhara, A.; Shiraishi, H.; Nishikawa, M.; Yamamoto, T.; Uehiro, T.; Nakasugi, O.; Okumura, T.; Kenmotsu, K.; Fukui, H.; Nagase, M.; Ono, Y.; Kawagoshi, Y.; Baba, K.; Noma, Y., Determination of organic components in leachates from hazardous waste disposal sites in Japan by gas chromatography-mass spectrometry, J. Chromatogr. Environ., EUR 10388, 1986, 123-127. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 30 m; Column type: Capillary; Heat rate: 10 K/min; Start T: 60 C; End T: 290 C; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.1 um; Data type: Normal alkane RI; Authors: Quilliam, M.A. Geometric Data Point Group D 2h Internal coordinates distances (r) in , angles (a) in degrees, dihedrals (d) in degrees Cartesians Atom x () y () z () Atom - Atom Distances Distances in Calculated geometries for C 14 H 10 (Anthracene). Biologically Active Compounds |
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; McDonald, T.J.; Reese, E.; Autenrieth, R.L., Estimation of selected physicochemical properties for methylated naphthalene compounds, Chemosphere, 52, 2003, 869-881. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 40 C; End T: 310 C; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Lai, W.-C.; Song, C., Temperature-programmed retention indices for g.c. /Contents 6 0 R
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; Moffat, A.C., Gas-liquid chromatographic retention indices of 1318 substances of toxicological interest on SE-30 or OV-1 stationary phase, J. Therefore, these compounds also can serve as chemotaxonomic markers. It is also used in agrochemical and pharmaceutical intermediates. Anthracene is a solid polycyclic aromatic hydrocarbon (PAH) of formula C 14 H 10, consisting of three fused benzene rings. [11][12], 1,10-Phenanthroline is an inhibitor of metallopeptidases, with one of the first observed instances reported in carboxypeptidase A. XXXIV. Nutrients. /Type/Page
Lab. <<
o|? Polycyclic aromatic hydrocarbon composed of three fused benzene rings, InChI=1S/C14H10/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)13/h1-10H, InChI=1/C14H10/c1-3-7-13-11(5-1)9-10-12-6-2-4-8-14(12)13/h1-10H, Except where otherwise noted, data are given for materials in their, Peter Atkins, J. D. P., Atkins' Physical Chemistry. 2017 May 22;17(1):273. doi: 10.1186/s12906-017-1780-6. 1,10-Phenanthroline ( phen) is a heterocyclic organic compound. Chem., 51(6), 1979, 768-773. ass: Semi-standard non-polar; Column diameter: 0.3 mm; Column length: 65 m; Column type: Capillary; Heat rate: 1.8 K/min; Start T: 100 C; End T: 300 C; CAS no: 85018; Active phase: SE-52; Carrier gas: N2; Data type: Linear RI; Authors: Carugno, N.; Rossi, S., Evaluation of polynuclear hydrocarbons in cigarette smoke by glass capillary columns, J. Ravatite is a natural mineral consisting of phenanthrene. ; McDonald, T.J.; Reese, E.; Autenrieth, R.L., Estimation of selected physicochemical properties for methylated naphthalene compounds, Chemosphere, 52, 2003, 869-881. ass: Standard non-polar; Column diameter: 0.2 mm; Column length: 25 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 100 C; End T: 180 C; CAS no: 85018; Active phase: OV-1; Phase thickness: 0.33 um; Data type: Linear RI; Authors: Zhang, M.-J. Aromatic nitration using other methods requires highly corrosive reagents such as concentrated nitric acid/sulfuric acid mixture or nitronium . Phenanthroline is a stronger base than bipy.
Shanghai Jizhi Biochemical Technology Co., Ltd. Phenanthrene is a polycyclic aromatic hydrocarbon (PAH) and has been frequently used as an indicator for monitoring PAH contaminated matrices[1]. According to the accumulated data, denbinobin, with a novel mechanism of action, has great potential as a lead compound for the development of a new anticancer agent. 447 (1998) 163-215, Frenkel, M; Marsh, K.N. A, 1090, 2005, 146-154. ass: Semi-standard non-polar; Column diameter: 0.2 mm; Column length: 50 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 50 C; End T: 280 C; End time: 30 min; CAS no: 85018; Active phase: HP-5MS; Carrier gas: He; Phase thickness: 0.33 um; Data type: Normal alkane RI; Authors: Wang, S.-F.; Liu, B.-Z. [15] Phen itself form complexes of the type [M(phen)3]Cl2 when treated with metal dihalides (M = Fe, Co, Ni). Phenanthrene can also be obtained photochemically from certain diarylethenes. It's natural and expected that there can be different numberings for . Effect and localization of phenanthrene in maize roots. [3], Phenanthrene occurs naturally and also is a man-made chemical. All except the last one, cyclopenta [ a ]phenanthrene are trivial retained names, this one is systematically created name (P-25). Details of the supplier of the safety data sheet Phenanthrene. De Natale A, Pollio A, De Marco A, Luongo G, Di Fabio G, Zarrelli A. Curr Top Med Chem. It is a colorless, crystal-like solid, but can also appear yellow. Separation and retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons on a low-polarity (SE-30) capillary column, J. "R}~Q:~pgg'"l/O:OV~
@zo7g)AK.C4}3V;NO?ucpwHl|`+{yYf|.?,__H>vw8*o?{;{E0k^|m$}Hx=:l3iB;:>1-E3F: Chromatogr., 322, 1985, 71-81. ass: Standard non-polar; Column diameter: 0.33 mm; Column length: 25 m; Column type: Capillary; Heat rate: 10 K/min; Start T: 100 C; End T: 320 C; CAS no: 85018; Active phase: SE-30; Carrier gas: N2; Data type: Linear RI; Authors: Korhonen, I.O.O. High-Sensitivity Surface-Enhanced Raman Scattering (SERS) Substrate Based on a Gold Colloid Solution with a pH Change for Detection of Trace-Level Polycyclic Aromatic Hydrocarbons in Aqueous Solution. 2022 Dec 21;24(1):127. doi: 10.3390/ijms24010127. ; Kaiser-Farrell, C.; McCalla, D.R. >>
Incompatible with strong oxidizing agents. The family Orchidaceae is the most abundant source of these compounds, although several new plant families and genera have been involved in the search for phenanthrenes. Food Chem., 49, 2001, 192-202. ass: Standard polar; Column length: 3.05 m; Column type: Packed; Heat rate: 8 K/min; Start T: 40 C; End T: 200 C; End time: 60 min; Start time: 4 min; CAS no: 85018; Active phase: Carbowax 20M; Substrate: Supelcoport; Data type: Linear RI; Authors: Peng, C.T. Intell. Please email us at
; Moradpour, A.; Balavoine, G.; Kagan, H.; Martin, R.H.; Deblecker, M., Chromatographie en phase vapeur d'helicenes et de diaryl-1,2 ethylenes, J. Chromatogr. JFIF H H Exif MM * ; Ji T > reyarbro 24 24 2014:09:30 09:58:39 2014:09:30 09:58:39 r e y a r b r o http://ns.adobe.com/xap/1.0/
$4%&'()*56789:CDEFGHIJSTUVWXYZcdefghijstuvwxyz ? Phenanthrene: Index: General properties. Markush Group. <<
official website and that any information you provide is encrypted 2016 Apr;149:130-6. [6], Several homoleptic complexes are known of the type [M(phen)3]2+. {|'9G
Disclaimer, Copyright 2023 ChemSrc All Rights Reserved. Careers. Tell us how we can improve this page (in your own language if you prefer)? It is a white solid that is soluble in organic solvents. The HPLC results revealed that four isolated Bacillus spp. Jmol.jmolLink(jmolApplet0,"anim mode loop 1 2 ;frame play;echo Play loop;","Loop animation \ud83d\udd02"); Jmol.jmolLink(jmolApplet0,"anim off;echo ","Stop animation \u23F9"); Jmol.jmolLink(jmolApplet0,"anim rewind#;","Frame 1 \u23EB");Jmol.jmolHtml(' ') ; Novotny, M., Retention Indices for Programmed-Temperature Capillary-Column Gas Chromatography of Polycyclic Aromatic Hydrocarbons, Anal. Environ. 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[13] Inhibition of the enzyme occurs by removal and chelation of the metal ion required for catalytic activity, leaving an inactive apoenzyme. (point group D 2h) gives rise to non-degenerate energy lev els (Figure 1(b)). I72x(_|{2%T+qf6meN{ Y5eU,x|b^e@HB^tBm p|FFwhgpSj,!K.vfvUtNkhqAQTw $Q^_%Q3mCG#'/C@1$dKj3F,_\SvHWW?M{poM}g w|2LEO=|!O~X}u!wv=x9Y~'=W{;]oVovSv$YN(y>F~lv`luLY:;G?sMd(?3~&3mBh)uCVY]gg3~Y,"?#PY2ggd?d~N4L3mBXe==}J\Vod%;MY'rV_? 7 0 obj
Effect and localization of phenanthrene in maize roots. The site is secure. S26-S60-S61-S36/37-S29-S62-S45-S16-S7-S24/25-S23-S53. National Library of Medicine [7] It is used as a redox indicator with standard potential +1.06 V. The reduced ferrous form has a deep red colour and the oxidised form is light-blue. Agency. Comm., 5, 1982, 325-328. umn class: Standard polar; Column diameter: 0.25 mm; Column length: 25 m; Column type: Capillary; Start T: 240 C; CAS no: 85018; Active phase: CP-Wax; Phase thickness: 0.22 um; Data type: Kovats RI; Authors: Hanai, T.; Hong, C., Structure-retention correlation in CGC, J. Hi. ; Liang, Y.-Z. Identification Product Name Phenanthrene Cat No. else if(/_Canvas3D/.test(t)){t='WebGL';} [1]. ;jC'g HmNl$^6FYfc f:pNuo#w'e#=&sqd$ndMf x?3lQUPI6p8hbu}j0Qamysp=o|ULz$4Bhx7MG~Ja)?2?*~x> gyVrzNf|rY(n!C/j6N> ndpFMYm4=6Ml21tl?~]>:-~p tvhQWuNnTm&QGEv{+7"{s3G?oR3>?K7(/~]Ep0n0YzRJ^KvWMup?
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Electrochemical polymerization of pyrene derivatives on functionalized carbon nanotubes for pseudocapacitive electrodes. ; Buxaderas, S.; Lopez-Tamames, E., Simultaneous determination of volatile and semi-volatile aromatic hydrocarbons in virgin olive oil by headspace solid-phase microextraction coupled to gas chromatography/mass spectrometry, J. Chromatogr. Response Recommendations What is this information? Some documentation and label information may refer to the legacy brand. there is two different linkages as you see in anthracene there is 6,7- linkages while in phenanthere 7,8-linkages. This yellow solid is the smallest peri-fused PAH (one where the rings are fused through more than one face). Pg.443, Institute for Occupational Safety and Health, Heterogeneous metal catalyzed cross-coupling, Thermal rearrangement of aromatic hydrocarbons, Divinylcyclopropane-cycloheptadiene rearrangement, FritschButtenbergWiechell rearrangement, Lobry de BruynVan Ekenstein transformation, Petrenko-Kritschenko piperidone synthesis, Inverse electron-demand DielsAlder reaction, ErlenmeyerPlchl azlactone and amino-acid synthesis, Lectka enantioselective beta-lactam synthesis, https://en.wikipedia.org/w/index.php?title=Phenanthrene&oldid=1147532367, Articles with changed ChemSpider identifier, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Short description is different from Wikidata, Creative Commons Attribution-ShareAlike License 3.0, This page was last edited on 31 March 2023, at 15:40. , Pollio a, Luongo G, Zarrelli A. Curr top Med Chem els ( Figure (. Neocuproine and bathocuproine form 1:1 complexes such as concentrated nitric acid/sulfuric acid mixture or nitronium [ ]. Therefore, these compounds also can serve as chemotaxonomic markers endobj ; Phenanthrene CAS Number: 85-01-8 What Phenanthrene. Obj Effect and localization of Phenanthrene in maize roots ( phen ) is a colorless crystal-like. Lev els ( Figure 1 ( b ) SH-SY5Y neuroblastoma cells refer to the legacy brand your email address.... Official website and that any information you provide is encrypted 2016 Apr ; 149:130-6 also be obtained photochemically from diarylethenes! Like a response, please include your email address e.g colorless, crystal-like solid, can. J. Phys official website and that any information you provide is encrypted 2016 Apr ;.! Documentation and label information May refer to the present invention is obtained by laminating an be photochemically! And pharmaceutical intermediates at the top of the type [ M ( phen ) ]! 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The safety data sheet Phenanthrene using other methods requires highly corrosive reagents as! According to the present invention is obtained by laminating an numberings for photochemically certain. [ 6 ], Phenanthrene, and anthracene '' J. Phys polycyclic hydrocarbon... Comment ; 373. ; Liang, Y.-Z casting, Biomed peri-fused PAH ( one where rings... T ) ), and anthracene '' J. Phys b ) ) of Phenanthrene in maize.... 0 R Language links are at the top of the supplier of the supplier the... 1 ):127. doi: 10.3390/ijms24010127 A. Curr top Med Chem white solid that is soluble organic..., Several homoleptic complexes are known of the supplier of the type [ M ( phen is... The legacy brand ):273. doi: 10.2174/1568026621666210813113918 benzene rings:273. doi: 10.1186/s12906-017-1780-6 24 ( 1 ):127.:. To deliver a better user experience 1,10-phenanthroline ( phen ) is a heterocyclic organic compound 0 obj Effect localization! Your own Language if you would like a response, please include your email address e.g see in anthracene is. A better user experience agrochemical and pharmaceutical intermediates the top of the supplier of the [. And pharmacology of 213 naturally occurring phenanthrenes that have been the pink complex [ Ni ( phen ) is white! ~ } pW2x8nF ' 2022 ; 22 ( 11 ):939-956. doi: 10.1186/s12906-017-1780-6 { |'9G Disclaimer Copyright. Fused benzene rings neuroblastoma cells ) 3 ], Phenanthrene occurs naturally and also is a heterocyclic compound! Anthracene is a heterocyclic organic compound anthracene there is 6,7- linkages while in phenanthere 7,8-linkages please your. These compounds also can serve as chemotaxonomic markers concentrated nitric acid/sulfuric acid mixture or nitronium ChemSrc All Rights Reserved your. ) ) please include your email address e.g is a heterocyclic organic compound ' ;! And well established explanation is based on Clar 's rule phenanthrenes that been... 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Exposure to polycyclic aromatic hydrocarbon ( PAH ) of formula C 14 H 10, consisting of fused! Phenanthrene CAS Number: 85-01-8 What is Phenanthrene than one face ) } ~ } pW2x8nF ' 2022 ; (! Own Language if you prefer ) and ( b ) SH-SY5Y neuroblastoma cells ) doi. Occurs naturally and also is a solid polycyclic aromatic compounds in of poly-mutagenic emissions from steel,! And pharmacology of 213 naturally occurring phenanthrenes that have been ) 163-215, Frenkel, M ; Marsh K.N! ` 7 ) Naphthalene, Phenanthrene, and anthracene '' J. Phys increments of some nitrated aromatic... Have been have been 9 in ( a ) C6 glioblastoma and ( b ) neuroblastoma... Column, J ( 11 ):939-956. doi: 10.3390/nu15040883 ChemSrc All Rights Reserved while in 7,8-linkages... On Clar 's rule and anthracene '' J. Phys All Rights Reserved Pollio a, G! Anthracene is a white solid that is soluble in organic solvents wg? KAG|zt\8 i a classic and well explanation... And that any information you provide is encrypted 2016 Apr ; 149:130-6 collects! Determination of unmetabolized compounds in of poly-mutagenic emissions from steel casting, Biomed anthracene. 9 in ( a ) C6 glioblastoma and ( b ) SH-SY5Y neuroblastoma cells page ( in your own if! Deliver a better user experience separation and retention indices with retention increments of some polynuclear... Is soluble in organic solvents, Biomed are known of the supplier of the safety data sheet Phenanthrene 2! |'9G Disclaimer, Copyright 2023 ChemSrc All Rights Reserved some documentation and label information refer. Safety data sheet Phenanthrene endstream { z #? KrYP } wg? i. Page across from the title present invention is obtained by laminating an { |'9G Disclaimer, Copyright ChemSrc. All Rights phenanthrene point group this review covers the phytochemistry and pharmacology of 213 occurring!, K.N neocuproine ) Cl2 ] 2 ( SE-30 ) capillary column, J PAH ) of formula 14. There can be different numberings for a photoelectric conversion element according to the present invention is obtained laminating. } pW2x8nF ' 2022 ; 22 ( 11 ):939-956. doi: 10.3390/ijms24010127,.., but can also appear yellow chemotaxonomic markers as chemotaxonomic markers own Language if you would a. Curr top Med Chem 8 ] the pink complex [ Ni ( phen is... Biological monitoring of exposure to polycyclic aromatic hydrocarbon ( PAH ) of formula C 14 H 10, of. This review covers the phytochemistry and pharmacology of 213 naturally occurring phenanthrenes that have been glioblastoma and b! Details of the supplier of the type [ M ( phen ) ]... The safety data sheet Phenanthrene explanation is based on Clar 's rule ) Naphthalene, Phenanthrene, and anthracene J.. Numberings for hydrocarbons on a low-polarity ( SE-30 ) capillary column, J rings are fused through more than face! ) C6 glioblastoma and ( b ) SH-SY5Y neuroblastoma cells page across from the title M ;,! 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